The compounds diethyl-N-carbazolylmethylphosphonate 1 and diethyl-2-oxymethylphosphonate carbazole 2 have been synthesised and characterized by a range of techniques including NMR, absorption and emission spectroscopy, infrared, and mass spectroscopy. Compound 1 forms a 2:1 complex 3 with calcium nitrate and the single crystal X-ray diffraction structure of 3 is described. Titrations of 1 with Zn2+ and Ca2+ in ethanol reveal that the intrinsic fluorescence is only slightly perturbed in the presence of these metal ions in micromolar ethanol solutions. Compounds 1 and 2 are readily taken up and visualized in L929 fibrosarcoma and DRG (Dorsal root ganglia) cell lines. 相似文献
In order to separate and pre-concentrate uranium from aqueous phase, a novel silica-based adsorbent was prepared by impregnating nalidixic acid (HNA) into a macroreticular silica/polymer composite support (SiO2-P) with a mean diameter of 60 μm. Adsorption behavior of uranium from aqueous solution onto the adsorbent was studied. Experimental results indicated that HNA/SiO2-P showed strong adsorption for uranium in a wide range of pH from 3.5 to 10.0, and the maximum adsorption capacity was 35.4 mg g−1. In addition, HNA/SiO2-P exhibited good selectivity for U(VI) and showed weak or bare adsorption affinity to foreign ions. Kinetic and isotherm of uranium adsorption were in accordance with the pseudo-second-order kinetic model and Langmuir isotherm adsorption model, respectively. Moreover, U(VI) sorption was found to be an endothermic reaction and spontaneous under experimental state. The synthesized adsorbent showed an admirable stability at lower pH values in aqueous solution.
Transition‐metal‐catalyzed C? H activation has recently emerged as a powerful tool for the functionalization of organic molecules. While many efforts have focused on the functionalization of arenes and heteroarenes by this strategy in the past two decades, much less research has been devoted to the activation of non‐acidic C? H bonds of alkyl groups. This Minireview highlights recent work in this area, with a particular emphasis on synthetically useful methods. 相似文献
Most democratic countries use apportionment methods to transform election results into whole numbers, which usually give the number of seats in a legislative body that the parties obtained. Which apportionment method does this best can be specified by measuring the error between the allocated result and the ideal proportion. We show how to find an apportionment method which is best suited to a given error function. We also discuss several properties of apportionment methods that have been labelled paradoxa. In particular we explain the highly publicised “Alabama” Paradox for the Hare/Hamilton method and show that other popular apportionment methods come with their very own paradoxa. 相似文献
An s-geodesic in a graph Γ is a path connecting two vertices at distance s. Being locally transitive on s-geodesics is not a monotone property: if an automorphism group G of a graph Γ is locally transitive on s-geodesics, it does not follow that G is locally transitive on shorter geodesics. In this paper, we characterise all graphs that are locally transitive on 2-geodesics, but not locally transitive on 1-geodesics. 相似文献
Drilling fluid has many functions, such as carry cuttings from the hole permitting their separation at the surface, cool and clean the bit, reduce friction between the drill pipe and wellbore, maintain the stability of the wellbore, and prevent the inflow of fluids from the wellbore and form a thin, low-permeable filter cake. Filter cake removal is an important step concerning both production and injection in wells, mainly concerning horizontal completion. The drilling fluids are typically comprised of starch, the most important component of the filter cake. A common approach to remove this filter cake is the use of acid solutions. However, these are non-specific reactants. A possible alternative is the use of enzymatic preparations, like amylases, that are able to hydrolyze starch. Wells usually operate in drastic conditions for enzymatic preparations, such as high temperature, high salt concentration, and high pressure. Thus, the main objective of this work was to characterize four enzymatic preparations for filter cake removal under open hole conditions. The results showed that high salt concentrations (204,000 ppm NaCl) in completion fluid decreased amylolytic activity. All enzymatic preparations were able to catalyze starch hydrolysis at all temperatures tested (30, 65, 80, and 95 °C). An increase of amylolytic activity was observed with the increase of pressure (100, 500 and 1,000 psi) for one commercial amylase. 相似文献